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In solid materials, non-trivial topological states, electron correlations and magnetism are central ingredients for realizing quantum properties, including unconventional superconductivity, charge and spin density waves and quantum spin liquids. The kagome lattice, made up of cornersharing triangles, can host these three ingredients simultaneously and has proved to be a fertile platform for studying diverse quantum phenomena including those stemming from the interplay of these ingredients. This Review introduces the fundamental properties of the kagome lattice and discusses the complex phenomena observed in several materials systems, including the intertwining of charge order and superconductivity in some kagome metals, the modulation of magnetism and topology in some kagome magnets, and the combination of symmetry breaking and Mott physics in ‘breathing’ kagome insulators. The Review also highlights open questions in the field and future research directions in kagome systems.more » « less
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Bravo, Moisés; McCandless, Gregory T.; Baumbach, Ryan E.; Wang, Yaojia; Ali, Mazhar N.; Chan, Julia Y. (, Inorganic Chemistry)
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Wang, Yaojia; McCandless, Gregory T.; Wang, Xiaoping; Thanabalasingam, Kulatheepan; Wu, Heng; Bouwmeester, Damian; van der Zant, Herre S.; Ali, Mazhar N.; Chan, Julia Y. (, Chemistry of Materials)
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Weiland, Ashley; Chaparro, David_G; Vergniory, Maia_G; Derunova, Elena; Yoon, Jiho; Oswald, Iain_W_H; McCandless, Gregory_T; Ali, Mazhar; Chan, Julia_Y (, APL Materials)The ZrSiS family of compounds has garnered interest as Dirac nodal-line semimetals and offers an approach to study structural motifs coupled with electronic features, such as Dirac crossings. CeSbTe, of the ZrSiS/PbFCl structure type, is of interest due to its magnetically tunable topological states. The crystal structure consists of rare earth capped square nets separating the magnetic Ce–Te layers. In this work, we report the single crystal growth, magnetic properties, and electronic structures of LnSb1−xBixTe (Ln = La, Ce, Pr; x ∼ 0.2) and CeBiTe, adopting the CeSbTe crystal structure, and the implication of tuning the electronic properties by chemical substitution.more » « less
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